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このブログでは、純粋な金属、合金、セラミックス、ミネラルなど希少な先端物質に関する幅広い知識についてのブログです。

Where Aluminum is Found

2017-11-03 14:27:22 | 純粋な金属
Aluminum is found in varying amounts in nature as aluminosilicates (contains aluminum, silicon, and oxygen) in various types of clay. As the minerals are weathered they gradually breakdown into various forms of hydrated aluminum oxide, Al2O3.xH2O, known as bauxite.
The bauxite is purified by the Bayer Process. First the ore is mixed with a hot concentrated solution of sodium hydroxide. The NaOH will dissolve the oxides of aluminum and silicon but not other impurities such as iron oxides, which remains insoluble. The insoluble materials are removed by filtration.

The solution which now contains the oxides of aluminum and silicon are next treated by bubbling carbon dioxide gas through the solution. Carbon dioxide forms a weak acid solution of carbonic acid which neutralizes the sodium hydroxide from the first treatment. This neutralization selectively precipitates the aluminum oxide, but leaves the silicates in solution. Again filtration is used for the separation. After this stage the purified aluminum oxide is heated to evaporate the water.

Aluminum in the metal form is very difficult to obtain by using some of the traditional chemical methods involving carbon or carbon monoxide as reducing agents to reduce the aluminum ions to aluminum metal. One of the earliest and costly methods in 1850 was to reduce aluminum chloride with sodium metal to obtain aluminum metal and sodium chloride. (Sodium metal is not easy to obtain either). As a result some of the earliest aluminum metal was made into jewelry.

The Use of Magnesium in Automotive

2017-11-03 14:22:37 |  化学物質のニュース
Today's interest in magnesium alloys for automotive applications is based on the combination of high strength properties and low density. In automotive applications weight reduction will improve the performance of a vehicle by reducing the rolling resistance and energy is used in acceleration, thus reducing fuel consumption and, moreover, a reduction in the greenhouse gas CO2 can be achieved.
In the 1920s magnesium began to make an appearance in the automotive industry. The light weight metal began to be used in racing car adding to their competitive edge. About a decade later, magnesium began to be used in commercial vehicles such as the Volkswagen Beetle which contained about 20kg (44.09lbs) of the material. Interest in using magnesium in automotive applications has increased over the past decade in response to the increasing environmental and legislative influences. Fuel efficiency, increased performance and sustainability are top-of-mind issues.

The use of magnesium in vehicles can, and does, lower overall weight and improves each of these conditions. Many large automotive companies have already replaced steel and aluminum with magnesium in various parts of their products. Audi, DaimlerChrysler (Mercedes-Benz), Ford, Jaguar, Fiat and Kia Motors Corporation are just a few of these companies. Magnesium is currently being used in gearboxes, steering columns and driver’s air bag housings as well as in steering wheels, seat frames and fuel tank covers.

The use of magnesium in automotive applications can provide more than just weight savings. For many years, the desire to identify challenges, solutions, and opportunities regarding the use of magnesium in vehicles has been growing. Magnesium usage on the front end of a vehicle provides not just a lower overall mass for the car, but also allows for the shifting of the center of gravity towards the rear improving the car’s handling and turning capabilities. In addition, frequencies that reduce vibration and overall noise can be achieved through the tuning of magnesium parts. Steel components in vehicles can be replaced by a single cast piece of magnesium adding to the strength of the material and allowing for housings to be cast into place. This castability also requires less tooling and fewer gauges, which lowers manufacturing costs.
According to the United States Automotive Materials Partnership (USAMP), it is estimated that by 2020, 350 lbs of magnesium will replace 500 lbs of steel and 130lbs of aluminum per vehicle, an overall weight reduction of 15%. In turn, this weight saving would lead to fuel savings of 9% to12% without any drastic changes in design. Considering the large number of vehicles produced worldwide, these weight savings could lead to a significant drop in the carbon dioxide released into the atmosphere, reducing its harmful impact on global warming. It is for this reason that magnesium is known as the green metal of the 21st century.
Currently, multiple automobile parts can be made from magnesium alloys such as engine block, wheels, steering columns, seats, front consoles, and hoods.
For more information, please visit http://www.samaterials.com/139-magnesium